ACAV A2 |
| Surface
chemistry
Surface chemistry determines rheology of coating
colors in low shear rate area (rotational viscometers).
There are both attractive and repulsive forces
between the particles.
The main forces are:
- Electric attraction/repulsion
- Van der Waals attraction
- Steric repulsion
If attractive forces are too strong, particles
tend to flocculate. Viscosity increases and suspension
becomes unstable. Other very important factor
is reactions between polymer chains and pigment/latex
particles. In low shear area clay coating colors
have usually higher viscosity than calcium carbonate
coating colors. For example CMC and clay form
strong structures.
The same applies to viscoelasticity. CMC and
clay tend to form structures stronger than starch
or carbonate. Surface chemistry and structure
formation are not so important at higher shear
rates, as structures break down under the shear.
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| © 2002
ACA Systems Ltd. - www.aca.fi |
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